I would consider going up to 3.50 to 3.70 gears, rather than 3.25. A 3.50 gear will put 16.6% more torque to the pavement at a given engine speed than the 3.00 gears you have now, which will be a noticeable improvement in acceleration. A 3.70 gear will give you a 23% improvement. Before headers, ignition, or ANYTHING else, I would put a set of high performance gears in the car.
Next on my list would be intake and carb. I guess I must have missed the Performer vs. Performer RPM stuff, but at the risk of offending someone (not sure who LOL!), I think you'd be wasting your money on the Performer; go with the Performer RPM, and maybe a 700 or 750 double pumper Holley carb. About this time you could also get the distributor curved for a quicker advance curve, and maybe upgrade to a better coil, or a CD ignition box like an MSD.
On the headers, +1 on the FPAs; they are worth it from a ground clearance perspective alone. A lot of guys like to get the headers done first, which is OK, but my dyno testing has proven (to me anyway) that there is more power to be had from the intake/carb combination than the headers.
Last on the list would be cam and valvetrain. Having said all that, there is something to be said for making all the engine modifications at once; then you only have to re-tune the car once, rather than after every change.
Good luck on the project - Jay