I've had several expansion tanks. The unit I use now, I completely dismantled it and removed all original solder and re-assembled it with high melt-point solder so I could powder coat it.
That being said, do you know the leak is at the point of contact between the tank flange and the intake manifold, as in the gasket area? If so, I've stopped several minor leaks in that area without removing the tank. Thoroughly dry the area, clean the area with some Brakleen, and then add a smear of your favorite color RTV.