Agree with Barry.
The jets are already a bit lean, most 850s usually run a 66, so I like the PV plan
As far as your choice on power valves though, I wouldn't go 4.5, that's likely too far the other way. My guess would be 5.5 or 6.5 but to be sure, I would recreate the 8:1 and see what you are pulling for vacuum at that load with a gauge hanging in the car and delay the PV a bit.
Typically, when I see a guy go 1/2 of idle vacuum or so, he has to compensate by jetting up, then it goes fat later, although that is a safe technique, it isn't right.
Also, realize that one of those could be bad, look for wet in the chamber behind it or test with vacuum. Having it THAT rich, is generally more than just PV timing
Other things like float level or plugged or bunged up air bleeds can add to it.
Finally, if recently apart, metering surfaces on the body can warp and cross channel, but to me it sounds at this point like you may have a PV issue