I have had a couple occasions where we experienced guide issues on iron heads. Might not apply to the original question, but worth noting.
First is that I have seen some valves that had obvious issues with the stem plating. Most valves will use a flash chrome plate on the stems for wear resistance. Chrome is really hard and can be pretty abrasive if it's not glass smooth. I've see a few where there was almost a gritty or bumpy finish. I've run a bit of 600 wet or dry & WD40 on those with the valve in a drill to smooth them out. At one time somebody sold a little grinding fixture to put a cross hatch on stems for high end race stuff.
I ran into an issue where we were sticking exhaust valves on the dyno during power runs. Often the valve would release once the engine cooled down. Using full bronze replacement guides. Ended up fixing it by opening up clearances a little and cutting back the portion of the guide that extends into the port a good bit. I think the bronze and iron had different expansion rates and the guide would tighten up on power runs as exhaust temperatures increased. I'm sure that the guide would have worn prematurely in a less aggressive environment as it "dragged" when hot rather than fully sticking.
Lesson is that surfaces need to be smooth and straight, and we don't need guide clearances to be super tight "just because we can".