Technically, the angle at the trans should equal the angle at the rear. Sort of saying the 'down' angle at the trans should be met with an equal "up" angle at the rear. The angles allow the u-joints to rotate on the roller pins vs spinning and wearing in one spot if the shaft, trans and rear were all in a straight line.
That said, if it has angles it's good. If they are not equal, it's not 100% efficient but nothing really is. Bad angle would be 90 degrees from the trans, meaning you broke something. On my door car, I never checked - just eyeballed it. Been good for the last 40 years. The dragster has zero pinion angle - just a coupler, no u-joints LOL! People that spend a lot of time bench racing pinion angles are wasting time IMHO. 2~4 gets it well enough.
As for adjustment, if there is no adjustment in the arms that control the rear location, I don't see how you could adjust it. In coil cars like a late model Mustang, they use adjustable control arms.