Wow! Very odd indeed. I'd grab a shop light and take a close look at any/all unplated, unpainted or chromed engine compartment stuff from the underside next. Then, under the rear end. Finally, the under dash back-o-the-gauges, wiring, etc. If none of them show any similar rusty signs, it's a puzzle.
Btw, do you have any drilled holes (yours or the cap's maker) in the ditzy cap to allow ionized air to escape, a common trick?