Just guessing on this Warren, because I don't run PCV valves, but adding the PCV valve may have an effect on A/F at idle. The carburetor is going to deliver fuel based on the vacuum drop above and below it. Addition of a PCV valve will decrease the vacuum in the manifold, resulting in a smaller vacuum signal at the carb and less fuel being delivered. So, it seems like the engine should run leaner. However, at idle the mixture screws on the carb are controlling the mixture, so adjustments there should get the A/F back where it belongs.
At part throttle or WOT, I would expect the vacuum leak from the PCV valve to be a very small percentage of the total airflow through the engine. So, it should have a negligible effect on A/F at cruise or WOT.